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ChemInform Abstract: Cyclization vs. Elimination Reactions of 5-Aryl-5-hydroxy 1,3-Diones: One-Pot Synthesis of 2-Aryl-2,3-dihydro-4H-pyran-4-ones.

✍ Scribed by Rasheed Ahmad Khera; Rasheed Ahmad; Ihsan Ullah; Obaid-Ur-Rahman Abid; Olumide Fatunsin; Muhammad Sher; Alexander Villinger; Peter Langer


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
42
Category
Article
ISSN
0931-7597

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Cyclization vs. Elimination Reactions of
✍ Rasheed Ahmadβ€…Khera; Rasheed Ahmad; Ihsan Ullah; Obaid-Ur-Rahman Abid; Olumide F πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 German βš– 222 KB πŸ‘ 1 views

## Abstract 2‐Aryl‐2,3‐dihydro‐4__H__‐pyran‐4‐ones were prepared in one step by cyclocondensation of 1,3‐diketone dianions with aldehydes. The use of HCl (10%) for the aqueous workup proved to be very important to avoid elimination reactions of the 5‐aryl‐5‐hydroxy 1,3‐diones formed as intermediate