ChemInform Abstract: Cyanocuprates Convert Carboxylic Acids Directly into Ketones.
β Scribed by Douglas T. Genna; Gary H. Posner
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 31 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The reaction of various carboxylic acids with excess cyanocuprates leads to ketone products whose yields depend on the substitution pattern of the organometal reagent.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Re 2 O 7 -Catalyzed Carbon-Carbon Bond Cleavage of Ketones into Carboxylic Acids with aq. TBHP. -Methyl and ethyl ketones are oxidized to the corresponding carboxylic acids in good yields using a catalytic amount of Re 2 O 7 and aq. tert.butyl hydroperoxide as oxidant. -
Direct Conversion of Carboxylic Esters into Ketones Using Organoaluminum Complexes. -In the presence of a stoichiometric amount of N,N'-dimethylethylenediamine, a direct and selective conversion of esters to ketones using trimethylaluminum is achieved. -(CHUNG, EUN-AE; CHO,