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ChemInform Abstract: Cu(I)-Binaphthyldiimine Catalyzed Asymmetric Cyclopropanation of Olefin with Diazoacetate.

✍ Scribed by H. SUGA; T. FUDO; T. IBATA


Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Cyclopro
✍ T. ICHIYANAGI; M. SHIMIZU; T. FUJISAWA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB

Asymmetric Cyclopropanation of Olefins with Diazoacetate Using Chiral Copper Catalysts. -Chiral 2-(2-sulfonylamino)phenyl-oxazolines and especially the oxazoline shown in A) are found to be efficient ligands for Cucatalyzed enantioselective cyclopropanation of olefins. The substitution pattern of th