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ChemInform Abstract: Asymmetric Cyclopropanation of Olefins with Diazoacetate Using Chiral Copper Catalysts.

✍ Scribed by T. ICHIYANAGI; M. SHIMIZU; T. FUJISAWA


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Asymmetric Cyclopropanation of Olefins with Diazoacetate Using Chiral Copper Catalysts. -Chiral 2-(2-sulfonylamino)phenyl-oxazolines and especially the oxazoline shown in A) are found to be efficient ligands for Cucatalyzed enantioselective cyclopropanation of olefins. The substitution pattern of the olefin as well as the nature of the ester group effect the stereochemical outcome. -(ICHIYANAGI, T.;


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