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ChemInform Abstract: Crystal Structures and Vibrational Spectroscopy of [NBu4][Cu(CN)X] (X: Br, I) and [NBu4][Cu3(CN)4]×CH3CN.

✍ Scribed by Graham A. Bowmaker; Hans Hartl; Victoria Urban

Publisher
John Wiley and Sons
Year
2001
Weight
37 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Synthetic Routes to Ga(CN)3 and MGa(CN)4 (M: Li, Cu) Framework Structures. -Pure crystalline Ga(CN)3 (III) is prepared in almost quantitative yield by reaction of (I) with either (II) or GaCl3. Structure determination by powder XRD and Rietveld refinement shows that (III) adopts a primitive cubic u