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ChemInform Abstract: Crystal Growth, Structure Determination and Magnetism of a New Hexagonal Rhodate: Ba9Rh8O24.

✍ Scribed by K. E. Stitzer; M. D. Smith; J. Darriet; H.-C. zur Loye

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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The new title compound is prepared from a mixture of CuO and Rh2O3 in a Bi2O3/V2O5 (3:1) flux (Pt crucible, 1373 K, 10 h). The compound crystallizes in the monoclinic space group C2/m with Z = 4 (single crystal XRD) and exhibits an unknown channel structure containing undulating layers of RhO6 octah