𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Conversion of N-Alkyldiisopropylamines into N,N-Bis(5-chloro-3-oxo[1,2]dithiol-4-yl)amines.

✍ Scribed by Susana Barriga; Lidia S. Konstantinova; Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. White; David J. Williams

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Conversion of N-Alkyldiisopropylamines into N, 2]dithiol-4-yl)amines.

-Reaction of N-alkyldiisopropylamines (I) and (IV) with excess S 2 Cl 2 and excess DABCO followed by hydrolysis with formic acid provides a novel way to N-alkylated N,N-bis(1,2-dithiol-4-yl)amines (II) and (V). Side products are the known tricyclic bis(dithiolo)thiazines (VI) except for the triisopropylamine (I), where the tricyclic product is sterically forbidden. The structure of compound (Va) is studied in detail using X-ray crystallographic analysis.

πŸ“œ SIMILAR VOLUMES

Synthesis and Crystal Structures of Bis(
Synthesis and Crystal Structures of Bis(tetraethylammonium)(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II) and Bis(tetra-n-butylammonium)(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II)
✍ Harald MΓΌller; Anna Puig Molina; B. Zh. Narymbetov; L. V. Zorina; S. S. Khasanov πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 112 KB πŸ‘ 1 views

The title compounds were prepared from 1,3,4,6tetrathiapentalene-2,5-dione (1) in one step via the in situ The X-ray single crystal structure of (Et 4 N) 2 [Zn(dmid) 2 ] (3 a) gave the tetragonal space group P4 3 2 1 2 with a = b = 13.810(2) A Ê , c = 16.480(3) A Ê , and Z = 4. (n-Bu 4 N) 2 [Zn(dmi