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ChemInform Abstract: Conversion of Aromatic Aldehydes into 1-Aryl-2,2-dichloroethenes.

โœ Scribed by V. G. Nenajdenko; A. V. Shastin; V. N. Korotchenko; E. S. Balenkova

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Thermal Conversion of 1-Alkynyl-1,2-dihydrophosphetes into Phosphinines. -Phosphetes (V), which are readily prepared by reaction of the appropriate titanacyclobutenes (III) with alkynyldichlorophosphines ( IV), rearrange to the corresponding phosphinines (VI) via an original 4ฯ€-cycloreversion-6ฯ€-el