ChemInform Abstract: Convergent Synthesis of Vitamin D3 Metabolites. Control of the Stereoselectivity in Samarium-Induced Cyclopropanations of Cyclopentenes.
β Scribed by M. M. KABAT; J. KIEGIEL; N. COHEN; K. TOTH; P. M. WOVKULICH; M. R. USKOKOVIC
- Book ID
- 112031884
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Preparation of Vitamin D Precursors Using the Intramolecular Coupling of Alkynes and Cyclopropylcarbene-Chromium Complexes: A Formal Total Synthesis of (Β±)-Vitamin D 3 . -The intramolecular coupling of the complexes (III) proceeds with high diastereoselectivity. Catalytic hydrogenati
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