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ChemInform Abstract: Convenient Preparation of Chiral trans-9,10-Dihydrophenanthrene-9,10-diamine.

✍ Scribed by Shuang-Zheng Lin; Tian-Pa You

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
41
Category
Article
ISSN
0931-7597

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From Central to Axial to Central Chirality: Enantioselective Construction of the trans-4,5,9,10-Tetrahydroxy-9,10-dihydrophenanthrene System
✍ Georgi Stavrakov; Manfred Keller; Bernhard Breit πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 278 KB

## Abstract Enantioselective synthesis of the core __trans__‐4,5,9,10‐tetrahydroxy‐9,10‐dihydrophenanthrene parent system of the antibiotics benanimicin, pradimicin and FD 594 has been accomplished. The synthesis employs a chiral tether approach and makes use of efficient central to axial to centra