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ChemInform Abstract: Contributions to the Crystal Chemistry of Uranium Tellurides. Part 4. The Crystal Structure of U0.9Te3.

✍ Scribed by K. STOEWE


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


1997 structure structure (solids and liquids) D 2000

28 -012

Contributions to the Crystal Chemistry of Uranium Tellurides. Part 4. The Crystal Structure of U0.9Te3.

-Reinvestigation of the binary uranium polytelluride described as ". beta.-modification" with the formula UTe3 and an NdTe3-type structure shows, that the brass-colored crystal obtained by transport reaction with TeBr4 is a nonstoichiometric compound. According to XRD, EDX, ICP-OES, and density measurements, it has an average composition of U0. 9Te3, according to the already known phase UTe3.38, and adopts the orthorhombic space group Cmcm with Z = 4. The structure is isotypic with NdTe3, however, with a statistical depletion of the U positions. -(STOEWE, K.; Z.


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