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ChemInform Abstract: Construction of Fused Oxonene Ring and Reproduction of Conformational Behavior Shown by Ring F of Ciguatoxin.

✍ Scribed by M. INOUE; M. SASAKI; K. TACHIBANA

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Construction of Fused Oxonene Ring and Reproduction of Conformational Behavior Shown by Ring F of Ciguatoxin.

-The SmI2-mediated intramolecular Reformatsky reaction of the O-linked bicyclic compound (II) provides the base for the construction of the trans-fused 6-9-6 tricyclic ether (V). The conformational alternation of the oxonene ring is reproduced as is observed for that in ciguatoxin ring F. -(INOUE, M.;

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