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ChemInform Abstract: Construction of 4-Hydroxy-2-pyridinones. Total Synthesis of (+)-Sambutoxin.

โœ Scribed by David R. Williams; Regis A. Turske

Publisher
John Wiley and Sons
Year
2001
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis of 6-Substituted-3-hydroxy-4(1H)-pyridinones: Oxidation-Michael Addition of 3-Hydroxy-4(1H)-pyridinones. -The oxidation of pyridinones of type (I) with Ag 2 O involving alcohols (II) is reported for the first time. The resulting pyridinediones subsequently undergo Michael addition with thi