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ChemInform Abstract: Conjugate Addition of Allyl Stannanes with Concomitant Triflation.

✍ Scribed by Ellen D. Beaulieu; Leah Voss; Dirk Trauner


Publisher
John Wiley and Sons
Year
2008
Weight
42 KB
Volume
39
Category
Article
ISSN
0931-7597

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Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides. -Allylic manganates, prepared in situ by transmetallation of allylstannanes with trimethylmanganate, react with epoxides, epoxy alcohols, and alkyl halides to give allylated products. -