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ChemInform Abstract: Condensation of 2-Naphthol and Naphthalenediols with o-Dichlorobenzene in the Presence of Aluminum Halides

โœ Scribed by Koltunov, Konstantin Yuryevich; Chernov, Aleksey Nikolaevich; Prakash, Gubbi Krishnamurthy Surya; Olah, George Andrew


Book ID
118754894
Publisher
John Wiley and Sons
Year
2012
Weight
35 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ionic Hydrogenation
โœ K. Yu. Koltunov; L. A. Ostashevskaya; I. B. Repinskaya ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Ionic Hydrogenation of 2-Naphthol and 1,7-Dihydroxynaphthalene with Cyclohexane in the Presence of Aluminum Halogenides. -As previously described, hydroxynaphthalene derivatives (I) and (III) activated by aluminum halogenides undergo hydrogenation in the presence of cyclohexane. As for 1-naphthol d

Condensation of naphthalenediols with be
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Isomeric 1,5-, 1,6-, 1,7-, 2,6-, and 2,7-naphthalenediols react smoothly with benzene at room temperature in the presence of an excess of aluminum bromide to give 5-, 6-, and 7-hydroxy-4-phenyl-1-tetralones and 5-and 6-hydroxy-4-phenyl-2-tetralones, respectively. The mechanism of these reactions is