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ChemInform Abstract: Concise Syntheses of Strychnine and Englerin A: The Power of Reductive Cyclizations Triggered by Samarium Iodide

โœ Scribed by Michal Szostak; David J. Procter


Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reductive Opening o
โœ A. NIVLET; V. LE GUEN; L. DECHOUX; T. LE GALL; C. MIOSKOWSKI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB

Reductive Opening of Cyclopropylogous ฮฑ-Hydroxy Aldehydes and Ketones by Samarium(II) Iodide. -The regioselectivity of the title reaction is found to be strongly dependant on the substitution pattern of the substrate. In several cases, a tandem cyclopropyl opening-deoxygenation reaction leads to ฮณ-