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ChemInform Abstract: Concise Substrate-Controlled Asymmetric Total Synthesis of (+)-3-(Z)-Dihydrorhodophytin.

โœ Scribed by Byungsook Kim; Te-ik Sohn; Sanghee Kim; Deukjoon Kim; Jongkook Lee

Publisher
John Wiley and Sons
Year
2011
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Total Sy
ChemInform Abstract: Asymmetric Total Synthesis of an Important 3-(Hydroxymethyl)carbacephalosporin.
โœ M. G. STOCKSDALE; S. RAMURTHY; M. J. MILLER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB

## Asymmetric Total Synthesis of an Important 3-(Hydroxymethyl)carbacephalosporin. -A short and practical asymmetric synthesis of the carbacephalosporin (VII), a potential intermediate for novel antibiotic agents, is reported. The route is based on the Mitsunobu cyclization of the dipeptide (III)