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ChemInform Abstract: Asymmetric Total Synthesis of an Important 3-(Hydroxymethyl)carbacephalosporin.

✍ Scribed by M. G. STOCKSDALE; S. RAMURTHY; M. J. MILLER

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Asymmetric

Total Synthesis of an Important 3-(Hydroxymethyl)carbacephalosporin.

-A short and practical asymmetric synthesis of the carbacephalosporin (VII), a potential intermediate for novel antibiotic agents, is reported. The route is based on the Mitsunobu cyclization of the dipeptide (III) and a Horner-Wadsworth-Emmons cyclization of the ketone (V). -(STOCKSDALE, M. G.; RAMURTHY, S.; MILLER, M.

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