ChemInform Abstract: Cleavage of N-O Bonds Promoted by Samarium Diiodide: Reduction of Free or N-Acylated O-Alkylhydroxylamines.
β Scribed by J. L. CHIARA; C. DESTABEL; P. GALLEGO; J. MARCO-CONTELLES
- Book ID
- 112032017
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
An efficient process for the redoctive cleavage of N-O bonds using samarium diiodide is detailed for a variety of slructural types to define the scope and limitations of the method. The reduction is shown to be compatible with base sensitive substrates such as lrifluoroacetamide derivatives, which c
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