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ChemInform Abstract: Reductive Cleavage of N-O Bonds in Hydroxylamine and Hydroxamic Acid Derivatives Using SmI2/THF.

โœ Scribed by G. E. KECK; S. F. MCHARDY; T. T. WAGER


Book ID
112025660
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Reductive cleavage of N๎—ธO bonds in hydro
โœ Gary E. Keck; Travis T. Wager; Stanton F. McHardy ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 887 KB

An efficient process for the redoctive cleavage of N-O bonds using samarium diiodide is detailed for a variety of slructural types to define the scope and limitations of the method. The reduction is shown to be compatible with base sensitive substrates such as lrifluoroacetamide derivatives, which c