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ChemInform Abstract: (Chlorosulfinyloxy)-N,N-dimethylmethaniminium Chloride Mediated Direct and Chemoselective Conversion of Carboxylic Acids into Aldehydes.

✍ Scribed by R. H. Khan; T. S. R. Prasada Rao

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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The Conversion of Saturated Hydrocarbons into Carboxylic Acids Using Fe(CO)5-H2O2 Oxidation. -Hydrocarbons such as cyclohexane or adamantane are transformed predominantly to homologous acids such as (I) and (II) with Fe(CO)5 and H2O2 in pyridine/HOAc. -(BARTON, D. H. R.;