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ChemInform Abstract: Chirality Transfer from Carbon to Nitrogen to Carbon via Cyclic Ammonium Ylides.

✍ Scribed by Kevin W. Glaeske; F. G. West


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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1,5-Hydrogen Transfers from Carbon to N-Tributyltin Substituted Nitrogen. -Treatment of the azides (I) with Bu3SnD generates N-tributyl substituted aminyl radicals which undergo an effective 1,5-H transfer. The reaction of (VI) under similar conditions results in competition of 1,5-H transfer and ra