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ChemInform Abstract: Chiral Squaric Prolinols: A New Type of Ligand for the Asymmetric Reduction of Prochiral Ketones by Borane.

✍ Scribed by Ji Zhang; Hai-Bing Zhou; Shou-Mao Lu; Mei-Ming Luo; Ru-Gang Xie; Michael C. K. Choi; Zhong-Yuan Zhou; Albert S. C. Chan; Teng-Kuei Yang


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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1997 stereochemistry stereochemistry (general, optical resolution) O 0030 30 -032 Chiral Thiourea as Ligand for the Asymmetric Reduction of Prochiral Ketones. -Prochiral ketones are reduced enantioselectively using the chiral thiourea ligand CTU with various metal catalysts. Best yields and selectiv