It was found that the oxirane ring is a functional group amenable to chiral discrimination by dirhodium-MTPA complexes. Considerable signal shifts up to 0.7 ppm are observed for 1 H nuclei close to the rhodium atoms in the complex. In analogy to previously reported olefins, this method appears to be
ChemInform Abstract: Chiral Recognition of Selenides and Iodides by 1H NMR Spectroscopy in the Presence of a Chiral Dirhodium Complex.
β Scribed by S. HAMEED; R. AHMAD; H. DUDDECK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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