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ChemInform Abstract: Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones.

✍ Scribed by Mei Wu; Cheng-Xia Miao; Shoufeng Wang; Xiaoxue Hu; Chungu Xia; Fritz E. Kuehn; Wei Sun

Book ID
112043681
Publisher
John Wiley and Sons
Year
2012
Weight
28 KB
Volume
43
Category
Article
ISSN
0931-7597

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Chiral Bioinspired Non-Heme Iron Complex
Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones
✍ Mei Wu; Cheng-Xia Miao; Shoufeng Wang; Xiaoxue Hu; Chungu Xia; Fritz E. Kühn; We 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 381 KB 👁 1 views

Chiral bioinspired iron complexes of N 4 ligands based on the ethylenediamine backbone display remarkable levels of enantioselectivity for the first time in the asymmetric epoxidation of a,b-unsaturated ketones using hydrogen peroxide (up to 87% ee) or peracetic acid as oxidant, respectively. Notabl