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ChemInform Abstract: Chiral Ancillaries in the Benzannulations of Alkoxy and Amino Carbene Complexes with Alkynes.

✍ Scribed by Richard P. Hsung; William D. Wulff; Steven Chamberlin; Ying Liu; Rui-Yang Liu; Huan Wang; John F. Quinn; Siu Ling B. Wang; Arnold L. Rheingold


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
32
Category
Article
ISSN
0931-7597

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✍ Chunrui Wu; Dmytro O. Berbasov; William D. Wulff πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 52 KB πŸ‘ 2 views

## Abstract It is found that chromium carbene complexes react much faster with terminal alkynes than with internal alkynes which allows highly selective formation of products of type (IV), (VII), and (XII) after oxidation.