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ChemInform Abstract: Synthesis of the Tetracyclic Carbon Core of Menogaril Utilizing the Benzannulation Reaction of a Fischer Carbene Complex and an Alkyne.

✍ Scribed by Jing Su; William D. Wulff; Richard G. Ball

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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## Abstract The first examples of insertion of a Cο£½C bond of an alkyne into a C~carbene~ο£ΏC~__Ξ±__~ single bond of a carbene complex (Cο£ΏC~__Ξ±__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~Mο£ΎC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo Cο£ΏC~__Ξ±__~ insertion of