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ChemInform Abstract: Chemoenzymatic Synthesis of Isotopically Labelled L-Valine, L- Isoleucine and allo-Isoleucine.

โœ Scribed by N. M. KELLY; R. G. REID; C. L. WILLIS; P. L. WINTON

Book ID
112033075
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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โœ John M. Humphrey; Jill A. Hart; A. Richard Chamberlin ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 401 KB

Diastereoselectively labeled (3S)-[4-13C]-L-valine and regioselectively labeled [3-ร‚3CH3]-L-isoleucine hydrochlorides were synthesized in 54% and 62% respective overall yields from L-aspartic acid. Carbon-13 labeled amino acids and their derivatives are important probes for the study of biochemical