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ChemInform Abstract: Chemoenzymatic Synthesis of (2R,5S)- and (2R,5R)-5-(1-Hydroxy-1- methylethyl)-2-methyl-2-vinyltetrahydrofuran (′Linalool Oxide′): Preparative Application of a Highly Selective Bacterial Epoxide Hydrolase.

✍ Scribed by M. MISCHITZ; K. FABER

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Chemoenzymatic Synthesis of (2R,5S)-and (2R,5R)-5-(1-Hydroxy-1methylethyl)-2-methyl-2-vinyltetrahydrofuran ('Linalool Oxide'): Preparative Application of a Highly Selective Bacterial Epoxide Hydrolase.

-The synthesis of the title compounds (V) and (VI) is based on a chemoenzymatic kinetic resolution of the epoxide (I). The use of a highly selective bacterial epoxide hydrolase for this purpose is reported. -

📜 SIMILAR VOLUMES

ChemInform Abstract: Pheromone Synthesis
ChemInform Abstract: Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)- and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae.
✍ H. TAKIKAWA; K. SHIMBO; K. MORI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Pheromone Synthesis. Part 183. Synthesis of (1R,2R,5S,7R)-and (1R,2S, 5S,7R)-2-Hydroxy-exo-brevicomin, the Components of the Male-Produced Volatiles of the Mountain Pine Beetle, Dendroctonus ponderosae. -Both title compounds (V) and (VI) are synthesized via asymmetric dihydroxylation as the key ste