ChemInform Abstract: Chemical, Photochemical and Enzymatic Approach to Furylhydroperoxides.
β Scribed by A. SCETTRI; F. BONADIES; A. LATTANZI; L. PALOMBI; S. PESCI
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Chemical, Photochemical and Enzymatic Approach to Furylhydroperoxides. -The desired hydroperoxides of type (II) are formed under the different conditions shown. In the presence of transition-metal compounds, however, their formation is followed by a Sharpless epoxidation. By-products (III) and/or (IV) are observed in all cases. -(SCETTRI, A.
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A Convenient Approach to Chiral Sulfoxides by Enantioselective Oxidation with a Steroidal Furylhydroperoxide. -Asymmetric oxidation of sulfides as well as kinetic resolution of racemic sulfoxides in the presence of the hydroperoxide shown in the scheme offer efficient routes to chiral sulfoxides. A