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ChemInform Abstract: A Convenient Approach to Chiral Sulfoxides by Enantioselective Oxidation with a Steroidal Furylhydroperoxide.

✍ Scribed by L. PALOMBI; F. BONADIES; A. PAZIENZA; A. SCETTRI

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Convenient Approach to Chiral Sulfoxides by Enantioselective Oxidation with a Steroidal Furylhydroperoxide.

-Asymmetric oxidation of sulfides as well as kinetic resolution of racemic sulfoxides in the presence of the hydroperoxide shown in the scheme offer efficient routes to chiral sulfoxides. Additionally, it is shown that the bornyl analogue of the hydroperoxide also affords satisfactory results in asymmetric oxidation and kinetic resolution.

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