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ChemInform Abstract: Characterization and Photochemistry of the Silane—Aluminum Complex Al×SiH4 and Its Photoproducts HAlSiH3 and AlSiH3 in a Solid Argon Matrix.

✍ Scribed by Benjamin Gaertner; Hans-Joerg Himmel

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Matrix Reactivity of Al and Ga Atoms (M)
Matrix Reactivity of Al and Ga Atoms (M) in the Presence of Silane: Generation and Characterization of the η2-Coordinated Complex M⋅SiH4, the Insertion Product HMSiH3, and the MI Species MSiH3 in a Solid Argon Matrix
✍ Benjamin Gaertner; Hans-Jörg Himmel; Victoria A. Macrae; Anthony J. Downs; Tim M 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 298 KB 👁 1 views

## Abstract Matrix isolation experiments give evidence for the formation of the loosely bonded metal–silane complex M⋅SiH~4~ by the spontaneous reaction of Al or Ga atoms (M) with silane in a solid Ar matrix at 12 K; however, Ga~2~ appears to insert spontaneously into an SiH bond to form HGaGaSiH~