ChemInform Abstract: Cationic-Oxazaborolidine-Catalyzed Enantioselective Diels—Alder Reaction of α,β-Unsaturated Acetylenic Ketones.
✍ Scribed by Joshua N. Payette; Hisashi Yamamoto
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 48 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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Diels-Alder Reactions of α,β-Unsaturated Thioesters and α,β-Unsaturated Selenoesters. -The regio-and exo/endo-selectivity of Diels-Alder reactions of thio-and selenoesters (II) with dienes is investigated. In general, thermal reactions show only low selectivities as expected. The selectivity improv