ChemInform Abstract: Catalytic Stereoselective Alkene Aziridination with Sulfonimidamides.
β Scribed by Fabien Robert-Peillard; Pablo H. Di Chenna; Chungen Liang; Camille Lescot; Florence Collet; Robert H. Dodd; Philippe Dauban
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 60 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Cuβcatalyzed treatment of olefins with the chiral substrate (I) allows stereoselective access to aziridines.
π SIMILAR VOLUMES
Catalytic Heterogeneous Aziridination of Alkenes Using Microporous Materials. -Copper-exchanged zeolite is successful in catalyzing aziridination of a range of alkenes employing Ph-I=N-Tos (II) as the nitrogen source. Modification of zeolite CuHY using a chiral ligand leads to preparation of the fi
## Abstract Various aziridineβ2βcarboxylic esters are prepared with high yields and enantioselectivities from imines, generated in situ from aldehydes and the amine (I), with ethyl diazoacetate (EDA).