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ChemInform Abstract: Catalytic Enantioselective Reactions. Part 6. A New Chiral Catalyst for Highly Enantioselective Addition of Diethylzinc to Aliphatic Aldehydes.

โœ Scribed by B. T. CHO; N. KIM; J.-H. KHOO

Book ID
112034890
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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New chiral catalysts for the highly enan
New chiral catalysts for the highly enantioselective addition of diethylzinc to aldehydes
โœ Myung-Jong Jin; Sum-Jin Ahn; Kyoung-Soo Lee ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 175 KB

Optically active amino thioacetate derivatives of (+l-norephedrine were found to act as effective catalysts for enantioselective addition of diethylzinc to aldehydes. This reaction provided optically active secondary alcohols with e.e. of up to >99%.