ChemInform Abstract: Catalytic Dicyanative 5-exo- and 6-endo-Cyclization Triggered by Cyanopalladation of Alkynes.
β Scribed by Shigeru Arai; Yuka Koike; Atsushi Nishida
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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Palladium-Catalyzed Cyclization of 2-Heteroyl-1-methylene-1,2,3,4tetrahydroisoquinolines. Studies on 6-endo-versus 5-exo-trig Cyclization. -In continuation of an earlier investigation the regioselectivity of the title cyclization is studied. If the corresponding bromide instead of the iodide (IV) i