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ChemInform Abstract: Catalytic Asymmetric Protonation of Chiral Calcium Enolates via 1,4-Addition of Malonates.

โœ Scribed by Thomas Poisson; Yasuhiro Yamashita; Shu Kobayashi


Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Efficient Asymmetri
โœ Gregorio Asensio; Pedro Aleman; Ana Cuenca; Jesus Gil; Mercedes Medio-Simon ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB

Efficient Asymmetric Protonation of Enolates with Readily Accessible Chiral ฮฑ-Sulfinyl Alcohols. -Under optimized conditions, ฮฑ-sulfinyl alcohols (Ia) and (Ib) afford the chiral ketones shown with good to excellent enantioselectivity. -(ASENSIO, GREGORIO; ALEMAN, PEDRO;