ChemInform Abstract: Efficient Asymmetric Protonation of Enolates with Readily Accessible Chiral α-Sulfinyl Alcohols.

✍ Scribed by Gregorio Asensio; Pedro Aleman; Ana Cuenca; Jesus Gil; Mercedes Medio-Simon

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199919029

✦ Synopsis

Efficient Asymmetric Protonation of Enolates with Readily Accessible Chiral α-Sulfinyl Alcohols.

-Under optimized conditions, α-sulfinyl alcohols (Ia) and (Ib) afford the chiral ketones shown with good to excellent enantioselectivity. -(ASENSIO, GREGORIO; ALEMAN, PEDRO;