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ChemInform Abstract: Catalytic Applications of Rhodium Complexes Containing Trialkylphosphines

✍ Scribed by M. C. SIMPSON; D. J. COLE-HAMILTON

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199709222

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## Abstract The bridge‐opening reaction of [(η^4^‐C~8~H~12~)~2~Rh~2~(μ‐Cl)~2~] with chiral and achiral β‐amino alcohol nucleophiles gave mononuclear complexes [(η^4^‐C~8~H~12~)RhCl{HN(R)∩OH‐κ__N__}] containing the amino alcohol ligands in N‐monodentate coordination; HN(R)∩OH = ethanolamine (4), 2‐a