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ChemInform Abstract: Catalytic Asymmetric Hydrosilylation with (Triazolinylidene)rhodium Complexes Containing an Axis of Chirality.

โœ Scribed by D. ENDERS; H. GIELEN; K. BREUER

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
29
Category
Article
ISSN
0931-7597

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Diastereoselective Synthesis of Chiral (
Diastereoselective Synthesis of Chiral (Triazolinylidene)rhodium Complexes Containing an Axis of Chirality
โœ Dieter Enders; Heike Gielen; Jan Runsink; Klaus Breuer; Stefan Brode; Karlheinz ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 289 KB ๐Ÿ‘ 1 views

Deprotonation of chiral triazolium salts 1 and reaction of the structure analysis. The application of the rhodium(COD) complexes as catalysts in an asymmetric hydrosilylation resulting nucleophilic carbenes with [(COD)RhCl] 2 or [(NBD)RhCl] 2 afforded square-planar complexes 2-6 in reaction has been