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ChemInform Abstract: Catalytic Activation of Trichlorosilane for Efficient and Stereoselective Reduction of Ketones.

✍ Scribed by Fumiaki Iwasaki; Osamu Onomura; Katsuhiko Mishima; Toshihide Maki; Yoshihiro Matsumura

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Alkoxy-Directed Rad
ChemInform Abstract: Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane.
✍ Eric J. Enholm; James P. Schulte II πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane. -A new highly diastereoselective reduction of Ξ±-hydroxy ketones with inexpensive HSiCl 3 gives predominantly anti 1,2-diols which are converted to ketals (III) and (V) for better separation of diastereomeric mixtures. Other silane