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A Simple and Efficient Catalytic Method for the Reduction of Ketones

✍ Scribed by Jesper Ekström; Jenny Wettergren; Hans Adolfsson

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
82 KB
Volume
349
Category
Article
ISSN
1615-4150

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## Abstract The palladacycle [Pd(__k__^__2__^__‐C__,__N__‐C(C~6~H~5~)C(Cl)CH~2~NMe~2~)(μ‐Cl)]~2~ (1) derived from the chloropalladation of 3‐(dimethylamino)‐1‐phenyl‐1‐propyne and its phosphine adduct [Pd(__k__^__2__^__‐C__,__N__‐C(C~6~H~5~)C(Cl)CH~2~NMe~2~)P(4‐CF~3~C~6~H~4~)~3~(Cl)] (3) promote