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ChemInform Abstract: Catalytic Activation of the Leaving Group in the SN2 Reaction.

✍ Scribed by Hirofumi Yamamoto; Ghanshyam Pandey; Yumiko Asai; Mayo Nakano; Atsushi Kinoshita; Kosuke Namba; Hiroshi Imagawa; Mugio Nishizawa

Publisher: John Wiley and Sons
Year: 2008
Weight: 46 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200812146

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## Abstract The __t__Bu‐P4 base was found to be an excellent catalyst for the activation of organozinc reagents. The base was used to promote the S~N~2′ reaction of α,β‐unsaturated esters bearing a γ‐chloride in the reactions with various organozinc reagents in the presence of LiCl. The reactions p