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ChemInform Abstract: Catalytic [3 + 2]-Cycloaddition of Dialkyl, Diallyl, and Dibenzyl Sulfides to Fullerene C60.

โœ Scribed by A. R. Tuktarov; A. R. Akhmetov; M. Pudas; A. G. Ibragimov; U. M. Dzhemilev

Publisher
John Wiley and Sons
Year
2008
Weight
15 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Phosphine-Catalyzed
ChemInform Abstract: Phosphine-Catalyzed Cycloaddition of Buta-2,3-dienoates and But-2- ynoates to (60)Fullerene.
โœ B. F. O'DONOVAN; P. B. HITCHCOCK; M. F. MEIDINE; H. W. KROTO; R. TAYLOR; D. R. M ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Phosphine-Catalyzed Cycloaddition of Buta-2,3-dienoates and But-2ynoates to (60)Fullerene. -Three phosphine catalysts are tested in the reaction of ( )fullerene ( I) with esters (II) and (IV). PBu3 is found to be the most reactive under the optimized reaction conditions. The structure of product (I