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ChemInform Abstract: Carbozincation of Dipolar Trimethylenemethane. A New Route to Functionalized Organozinc Reagents.

โœ Scribed by Masaharu Nakamura; Naohiko Yoshikai; Eiichi Nakamura


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Alkylations of Functionalized Organozinc Reagents with Allylic Epoxides Catalyzed by a Cyanocuprate. -Transmetalation of the title reagents with either LiCuCN(Me) or Li2CuCN(Me)2 affords a cyanocuprate which selectively transfers the zinc substituents to allylic epoxides, thus establishing a novel