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ChemInform Abstract: Carbonyl Complexes of Rhodium- and Iridium-Containing Nitrogen and Nitrogen—Oxygen Donor Ligands: Reactivity and Catalytic Carbonylation of Alcohol

✍ Scribed by Dipak Kumar Dutta

Book ID
112048726
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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The dimeric rhodium precursor [Rh(CO) 2 Cl] 2 reacts with two molar equivalent of 9,9-dimethyl-4,5bis (diphenylphosphino)xanthene [xantphos] (a), bis(2-diphenylphosphinophenyl)ether [DPEphos] (b) and their corresponding dioxide analogues xantphos dioxide (c), DPEphos dioxide (d) to afford the monoan