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ChemInform Abstract: C-Glycosyl Compounds from Free Radical Reactions

โœ Scribed by B. GIESE; H.-G. ZEITZ


Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
โœ H.-D. JUNKER; W.-D. FESSNER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Diastereoselective Synthesis of C-Glycosylphosphonates via Free-Radical Glycosylation. -C-glycosidic sugar phosphonates (III) are prepared in a single step by addition of free radicals derived from the bromides (I) to dialkyl vinylphosphonates. In most cases, high ฮฑ-selectivity at the reaction cent