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ChemInform Abstract: Biocatalytic Kinetic Resolution of Hydroperoxy Vinylsilanes by Horseradish Peroxidase (HRP) and Lipases, a Comparative Study.

✍ Scribed by W. ADAM; C. MOCK-KNOBLAUCH; C. R. SAHA-MOELLER


Book ID
101851764
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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Biocatalytic kinetic resolution of hydro
✍ Waldemar Adam; Cordula Mock-Knoblauch; Chantu R. Saha-MΓΆller πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 244 KB

The kinetic resolution of hydroperoxy vinylsilanes 1 has been investigated by the horseradish-peroxidase(HRP)-catalyzed reduction with guaiacol and by the acetylation with isopropenyl acetate in the presence of various lipases. The best results (ee values up to 89% at 48% conversion) were obtained f