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ChemInform Abstract: Behavior of α-Carbethoxy Radical Generated from the Ester of N- Hydroxy-2-thiopyridone.

✍ Scribed by R. BORAH; J. C. SARMA


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Generation of α-Bor
✍ K. TAKAI; N. SHINOMIYA; M. OHTA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

## Generation of α-Boryl Radicals by Reduction of α-Haloalkylboronic Esters with CrCl 2 . -Reduction of α-haloakylboronic esters (I) under optimized conditions generates α-boryl radicals, which readily react with electron-deficient olefins to yield the adducts (III) under mild conditions. -