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ChemInform Abstract: BaYbSi4N7 - Unexpected Structural Opportunities in Nitridosilicates.

✍ Scribed by H. HUPPERTZ; W. SCHNICK


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Edge-Sharing SiN4 T
✍ H. HUPPERTZ; W. SCHNICK πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB

Edge-Sharing SiN4 Tetrahedra in the Highly Condensed Nitridosilicate BaSi7N10. -Transparent, colorless crystals of the novel title compound are prepared by reaction of Ba and Si(NH)2 at 1650 β€’ C in a highfrequency furnace. The structure (monoclinic, Pc, Z = 2), as determined by single-crystal XRD,